Biosynthesis of trihothecenes and apotrichothecenes.
ZAMIR, L.O., NIKOLAKAKIS, A., SAURIOLF, and MAMER, O.
Journal of agricultural and food Chemistry 47: 1823-1835
1999
บทคัดย่อ
The first two oxygenation steps posttrichodiene in the biosyntheses of 3-acetylDON and sambucinol were investigated. It was shown that 2 alphahydroxytrichodiene is the first oxygenated step in the biosynthesis of both 3-acetylDON and sambucinol. It was also demonstrated that the dioxygenated 12, 13-epoxy-9, 10-trichoene-2-alpha-ol is a biosynthetic precursor to trichothecenes.