Formal total synthesis of ( /-)-aflatoxin B2 utilizing the rhodium carbenoid dipolar cycloaddition.
PIRRUNG, M.C. and LEE, Y.R.
Tetrahedron Letters 37 : 2391-2394.
1996
บทคัดย่อ
Formal total synthesis of (+/-)-aflatoxin B2 utilizing the rhodium
carbenoid dipolar cycloaddition.
A formal total
synthesis of (+/-)AFB2
has been completed using as the key step the rhodium-mediated dipolar
cycloaddition of a cyclic rhodium carbenoid to dihydrofuran.